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Relative rates for hydrogen abstraction from positions C10 and C13 by human 15-lipoxygenase-1 and various arachidonic acid analogs. Error bars are indicated in parentheses.
| Conditions | kC13 (s−1) | kC10 (s−1) |
|---|---|---|
| 15-hLO-1 and AA | k13H = 8.8 (0.3) | k10H = 1.10 (0.10) |
| 15-hLO-1 and 10-d2-AA | k13H = 9.0 (0.3) | k10D = 0.26 (0.01) |
| 15-hLO-1 and 13-d2-AA | k13D = 0.62 (0.08) | k10H = 1.87 (0.15) |
| 15-hLO-1 and 10,13-d4-AA | k13D = 0.91 (0.08) | k10D = 0.09 (0.01) |
